Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV)
The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The...
| Authors: | ; ; |
|---|---|
| Format: | Dataset |
| Status: | Published version |
| Publication date: | 2019 |
| Country: | España |
| Institution: | Consorcio Madroño |
| Repository: | e-cienciaDatos, Repositorio de Datos del Consorcio Madroño |
| OAI Identifier: | doi:10.21950/BCYB9Y |
| Online Access: | https://doi.org/10.21950/BCYB9Y |
| Access Level: | Open access |
| Keyword: | Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| _version_ | 1878736562917736449 |
|---|---|
| author | Pérez Redondo, Adrián |
| author2 | Varela-Izquierdo, Víctor Yélamos, Carlos |
| author2_role | author author |
| author_browse | Pérez Redondo, Adrián Varela-Izquierdo, Víctor Yélamos, Carlos |
| author_facet | Pérez Redondo, Adrián Varela-Izquierdo, Víctor Yélamos, Carlos |
| author_role | author |
| collection | e-cienciaDatos, Repositorio de Datos del Consorcio Madroño |
| description | The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant intermolecular interactions present between the molecules in the crystal structure. |
| eu_rights_str_mv | openAccess |
| format | dataset |
| id | ES_9137c0d1c2f2d40ff5d0f3f7a35f1931 |
| institution | Consorcio Madroño |
| instname_str | Consorcio Madroño |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | doi:10.21950/BCYB9Y |
| publishDate | 2019 |
| publishDateSort | 2019 |
| publisher | e-cienciaDatos |
| publisherStr | e-cienciaDatos |
| reponame_str | e-cienciaDatos, Repositorio de Datos del Consorcio Madroño |
| spelling | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) Pérez Redondo, Adrián Varela-Izquierdo, Víctor Yélamos, Carlos Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant intermolecular interactions present between the molecules in the crystal structure. e-cienciaDatos https://doi.org/10.21950/BCYB9Y |
| spellingShingle | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) Pérez Redondo, Adrián Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| status_str | publishedVersion |
| title | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| title_full | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| title_fullStr | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| title_full_unstemmed | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| title_short | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| title_sort | Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV) |
| topic | Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| topic_facet | Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| url | https://doi.org/10.21950/BCYB9Y |