Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV)
The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The...
| Authors: | ; ; |
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| Format: | Dataset |
| Status: | Published version |
| Publication date: | 2019 |
| Country: | España |
| Institution: | Consorcio Madroño |
| Repository: | e-cienciaDatos, Repositorio de Datos del Consorcio Madroño |
| OAI Identifier: | doi:10.21950/BCYB9Y |
| Online Access: | https://doi.org/10.21950/BCYB9Y |
| Access Level: | Open access |
| Keyword: | Chemistry Crystal structure Hafnium Cyclopentadienyl ligand Organometallic compound. |
| Summary: | The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant intermolecular interactions present between the molecules in the crystal structure. |
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