Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observe...
| Autores: | ; ; ; ; ; ; ; |
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| Tipo de documento: | Artículo |
| Estado: | Published version |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/136998 |
| Acceso en línea: | https://hdl.handle.net/11441/136998 https://doi.org/10.1039/d0dt02326d |
| Nivel de acceso: | Acceso abierto |
| _version_ | 1878732405625323521 |
|---|---|
| author | Sánchez Mellado, Práxedes |
| author2 | Hernández Juárez, Martín Rendón Márquez, Nuria López Serrano, Joaquín López Santos, Laura Álvarez González, Eleuterio Paneque Sosa, Margarita Suárez Escobar, Andrés Luis |
| author2_role | author author author author author author author |
| author_browse | Hernández Juárez, Martín López Santos, Laura López Serrano, Joaquín Paneque Sosa, Margarita Rendón Márquez, Nuria Suárez Escobar, Andrés Luis Sánchez Mellado, Práxedes Álvarez González, Eleuterio |
| author_facet | Sánchez Mellado, Práxedes Hernández Juárez, Martín Rendón Márquez, Nuria López Serrano, Joaquín López Santos, Laura Álvarez González, Eleuterio Paneque Sosa, Margarita Suárez Escobar, Andrés Luis |
| author_role | author |
| collection | idUS. Depósito de Investigación de la Universidad de Sevilla |
| description | Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_42710ea0b5f7b05ae3c8d3e43ba0a7ce |
| institution | Universidad de Sevilla (US) |
| instname_str | Universidad de Sevilla (US) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:idus.us.es:11441/136998 |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | Royal Society of Chemistry |
| publisherStr | Royal Society of Chemistry |
| reponame_str | idUS. Depósito de Investigación de la Universidad de Sevilla |
| spelling | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands Sánchez Mellado, Práxedes Hernández Juárez, Martín Rendón Márquez, Nuria López Serrano, Joaquín López Santos, Laura Álvarez González, Eleuterio Paneque Sosa, Margarita Suárez Escobar, Andrés Luis Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions. (FEDER contribution) from the Spanish Ministry of Science and Innovation (CTQ2016-80814-R) Junta de Andalucía (PY18-3208) Royal Society of Chemistry https://hdl.handle.net/11441/136998 https://doi.org/10.1039/d0dt02326d |
| spellingShingle | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands Sánchez Mellado, Práxedes |
| status_str | publishedVersion |
| title | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| title_full | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| title_fullStr | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| title_full_unstemmed | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| title_short | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| title_sort | Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands |
| url | https://hdl.handle.net/11441/136998 https://doi.org/10.1039/d0dt02326d |