Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observe...

Full description

Authors: Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; López Santos, Laura; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis
Format: Article
Status:Published version
Publication date:2020
Country:España
Institution:Universidad de Sevilla (US)
Repository:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/136998
Online Access:https://hdl.handle.net/11441/136998
https://doi.org/10.1039/d0dt02326d
Access Level:Open access
Summary:Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.

Similar Items