Implementation of an alternative method to determine the critical cooling rate: Application in silver and copper nanoparticles

An alternative method to determine the critical cooling rate of materials has been developed by explaining the size and cooling rate dependences of physical properties of metallic nanoparticles through the scaling theory. This method has been applied to silver and copper nanoparticles which have bee...

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Bibliographic Details
Authors: Medrano L.R.; Landauro C.V.; Rojas-Tapia J.
Format: Article
Publication date:2014
Country:Perú
Institution:CONCYTEC
Repository:CONCYTEC-Institucional
Language:English
OAI Identifier:oai:repositorio.concytec.gob.pe:20.500.12390/651
Online Access:https://hdl.handle.net/20.500.12390/651
https://doi.org/10.1016/j.cplett.2014.08.044
Access Level:Open access
Keyword:Silver
Cooling
Metal nanoparticles
Molecular dynamics
Cooling rates
Copper nanoparticles
Critical cooling rate
Metallic nanoparticles
Molecular dynamics simulations
Physical quantities
Scaling theories
Description
Summary:An alternative method to determine the critical cooling rate of materials has been developed by explaining the size and cooling rate dependences of physical properties of metallic nanoparticles through the scaling theory. This method has been applied to silver and copper nanoparticles which have been obtained by molecular dynamics simulations. The results reveal that our values for critical rate are close for each studied physical quantity. Thus, by taking the average among them, we obtain 6.2(8) × 1012 K/s for silver and 8.9(5) × 1012 K/s for copper. We have also found the threshold size of nanoparticle behavior is independent of the cooling rate.