Cyclic C-F-Metal Containig Species. Solid State and Computational Examples
This article examines the results of research published be- tween 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environm...
| Autores: | ; |
|---|---|
| Tipo de documento: | Artículo |
| Estado: | Published version |
| Fecha de publicación: | 2013 |
| País: | México |
| Institución: | UNAM |
| Repositorio: | Redalyc-UNAM |
| OAI Identifier: | oai:redalyc.org:47527856012 |
| Acceso en línea: | https://www.redalyc.org/articulo.oa?id=47527856012 |
| Nivel de acceso: | Acceso abierto |
| Palabra clave: | Química Carbon theory fluorine structure bond activation |
| _version_ | 1878407825892311041 |
|---|---|
| author | Maribel Arroyo Carranza |
| author2 | Hugo Torrens Miquel |
| author2_role | author |
| author_browse | Hugo Torrens Miquel Maribel Arroyo Carranza |
| author_facet | Maribel Arroyo Carranza Hugo Torrens Miquel |
| author_role | author |
| collection | Redalyc-UNAM |
| description | This article examines the results of research published be- tween 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environments have been gathered. A similar analysis brings together almost 40 transitional states and intermediates resulting from theoretical work studying the transition metal mediated carbon-fluorine bond activation. Among other aspects, this review is useful to recognize the specific characteristics which determine whether the C-F activation process is carried out through a concerted process, a mechanism assisted by auxiliary ligands or by free radicals. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | MX_1ab7d783cfd689fcc674b81242e0c07e |
| identifier_str_mv | 1870-249X |
| institution | UNAM |
| instname_str | Universidad Nacional Autónoma de México |
| network_acronym_str | MX |
| network_name_str | México |
| oai_identifier_str | oai:redalyc.org:47527856012 |
| publishDate | 2013 |
| publishDateSort | 2013 |
| publisher | Sociedad Química de México |
| publisherStr | Sociedad Química de México |
| reponame_str | Redalyc-UNAM |
| spelling | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples Maribel Arroyo Carranza Hugo Torrens Miquel Química Carbon theory fluorine structure bond activation This article examines the results of research published be- tween 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environments have been gathered. A similar analysis brings together almost 40 transitional states and intermediates resulting from theoretical work studying the transition metal mediated carbon-fluorine bond activation. Among other aspects, this review is useful to recognize the specific characteristics which determine whether the C-F activation process is carried out through a concerted process, a mechanism assisted by auxiliary ligands or by free radicals. Sociedad Química de México 1870-249X https://www.redalyc.org/articulo.oa?id=47527856012 |
| spellingShingle | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples Maribel Arroyo Carranza Química Carbon theory fluorine structure bond activation |
| status_str | publishedVersion |
| title | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| title_full | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| title_fullStr | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| title_full_unstemmed | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| title_short | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| title_sort | Cyclic C-F-Metal Containig Species. Solid State and Computational Examples |
| topic | Química Carbon theory fluorine structure bond activation |
| topic_facet | Química Carbon theory fluorine structure bond activation |
| url | https://www.redalyc.org/articulo.oa?id=47527856012 |