Microheterogeneous catalysis
The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have been reviewed. In these microheterogeneous systems the observed changes in the ra...
| Autores: | ; ; |
|---|---|
| Tipo de documento: | Artigo |
| Estado: | Published version |
| Data de publicação: | 2010 |
| País: | España |
| Recursos: | Universidad de Sevilla (US) |
| Repositório: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/95238 |
| Acesso em linha: | https://hdl.handle.net/11441/95238 https://doi.org/10.3390/molecules15074815 |
| Nível de acesso: | Acesso aberto |
| Palavra-chave: | microheterogeneous catalysis micelle polymer cyclodextrin photochemistry |
| _version_ | 1878742795180572672 |
|---|---|
| author | Bernal Pérez, Eva |
| author2 | Marchena Barriento, María José Sánchez Burgos, Francisco |
| author2_role | author author |
| author_browse | Bernal Pérez, Eva Marchena Barriento, María José Sánchez Burgos, Francisco |
| author_facet | Bernal Pérez, Eva Marchena Barriento, María José Sánchez Burgos, Francisco |
| author_role | author |
| collection | idUS. Depósito de Investigación de la Universidad de Sevilla |
| description | The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have been reviewed. In these microheterogeneous systems the observed changes in the rate constants have been rationalized using the Pseudophase Model. This model produces equations that can be derived from the Brönsted equation, which is the basis for a more general formulation of catalytic effects, including electrocatalysis. When, in the catalyzed reaction one of the reactants is in the excited state, the applicability (at least formally) of the Pseudophase Model occurs only in two limiting situations: the lifetime of the fluorophore and the distributions of the quencher and the probe are the main properties that define the different situations. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_fc69760b3c78cceb33fd4e1f8ab98aeb |
| institution | Universidad de Sevilla (US) |
| instname_str | Universidad de Sevilla (US) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:idus.us.es:11441/95238 |
| publishDate | 2010 |
| publishDateSort | 2010 |
| publisher | MDPI |
| publisherStr | MDPI |
| reponame_str | idUS. Depósito de Investigación de la Universidad de Sevilla |
| spelling | Microheterogeneous catalysis Bernal Pérez, Eva Marchena Barriento, María José Sánchez Burgos, Francisco microheterogeneous catalysis micelle polymer cyclodextrin photochemistry The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have been reviewed. In these microheterogeneous systems the observed changes in the rate constants have been rationalized using the Pseudophase Model. This model produces equations that can be derived from the Brönsted equation, which is the basis for a more general formulation of catalytic effects, including electrocatalysis. When, in the catalyzed reaction one of the reactants is in the excited state, the applicability (at least formally) of the Pseudophase Model occurs only in two limiting situations: the lifetime of the fluorophore and the distributions of the quencher and the probe are the main properties that define the different situations. D.G.I.C.Y.T. (CTQ2008-00008/BQU) MDPI https://hdl.handle.net/11441/95238 https://doi.org/10.3390/molecules15074815 |
| spellingShingle | Microheterogeneous catalysis Bernal Pérez, Eva microheterogeneous catalysis micelle polymer cyclodextrin photochemistry |
| status_str | publishedVersion |
| title | Microheterogeneous catalysis |
| title_full | Microheterogeneous catalysis |
| title_fullStr | Microheterogeneous catalysis |
| title_full_unstemmed | Microheterogeneous catalysis |
| title_short | Microheterogeneous catalysis |
| title_sort | Microheterogeneous catalysis |
| topic | microheterogeneous catalysis micelle polymer cyclodextrin photochemistry |
| topic_facet | microheterogeneous catalysis micelle polymer cyclodextrin photochemistry |
| url | https://hdl.handle.net/11441/95238 https://doi.org/10.3390/molecules15074815 |