Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent
A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established prot...
| Authors: | ; ; ; ; |
|---|---|
| Format: | Article |
| Status: | Accepted version |
| Publication date: | 2017 |
| Country: | España |
| Institution: | Universidad de Burgos (UBU) |
| Repository: | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| OAI Identifier: | oai:riubu.ubu.es:10259/4528 |
| Online Access: | http://hdl.handle.net/10259/4528 |
| Access Level: | Open access |
| Keyword: | amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic |
| _version_ | 1878742541748142080 |
|---|---|
| author | Rubio Presa, Rubén |
| author2 | Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto |
| author2_role | author author author author |
| author_browse | Arnáiz García, Francisco Javier Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Rubio Presa, Rubén Sanz Díez, Roberto |
| author_facet | Rubio Presa, Rubén Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto |
| author_role | author |
| collection | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| description | A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_f7ccb7d38ee2eba6cfaa4d8dbac9e501 |
| institution | Universidad de Burgos (UBU) |
| instname_str | Universidad de Burgos (UBU) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:riubu.ubu.es:10259/4528 |
| publishDate | 2017 |
| publishDateSort | 2017 |
| publisher | Wiley-VCH Verlag |
| publisherStr | Wiley-VCH Verlag |
| reponame_str | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| spelling | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent Rubio Presa, Rubén Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases. Ministerio de Economı´ayCompetitividad (MINECO) (CTQ2013-48937-C2-1-P,CTQ2015-70371-REDT, and CTQ2016-75023-C2-1-P) andJunta de Castilla y Leo´n and FEDER (BU076U16) This is the peer reviewed version of the following article: R. Rubio-Presa, M. A. Fernández-Rodríguez, M. R. Pedrosa, F. J. Arnáiz, R. Sanz, Adv. Synth. Catal. 2017, 359, 1752. doi: 10.1002/adsc.201700071, which has been published in final form at 10.1002/adsc.201700071. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving Wiley-VCH Verlag http://hdl.handle.net/10259/4528 |
| spellingShingle | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent Rubio Presa, Rubén amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic |
| status_str | acceptedVersion |
| title | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| title_full | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| title_fullStr | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| title_full_unstemmed | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| title_short | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| title_sort | Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent |
| topic | amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic |
| topic_facet | amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic |
| url | http://hdl.handle.net/10259/4528 |