Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes
Readily available o′-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evoluti...
| Authors: | ; ; ; ; ; |
|---|---|
| Format: | Article |
| Status: | Accepted version |
| Publication date: | 2020 |
| Country: | España |
| Institution: | Universidad de Burgos (UBU) |
| Repository: | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| OAI Identifier: | oai:riubu.ubu.es:10259/5546 |
| Online Access: | http://hdl.handle.net/10259/5546 |
| Access Level: | Open access |
| Keyword: | Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Química orgánica Chemistry, Organic |
| _version_ | 1878741538159198208 |
|---|---|
| author | Milián, Ana |
| author2 | García García, Patricia Pérez Redondo, Adrián Sanz Díez, Roberto Vaquero, Juan J. Fernández Rodríguez, Manuel A. |
| author2_role | author author author author author |
| author_browse | Fernández Rodríguez, Manuel A. García García, Patricia Milián, Ana Pérez Redondo, Adrián Sanz Díez, Roberto Vaquero, Juan J. |
| author_facet | Milián, Ana García García, Patricia Pérez Redondo, Adrián Sanz Díez, Roberto Vaquero, Juan J. Fernández Rodríguez, Manuel A. |
| author_role | author |
| collection | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| description | Readily available o′-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evolution of the gold intermediate and plays a key role in the reaction outcome. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_e6f32b7e4bf689c2009fa4504fc93948 |
| institution | Universidad de Burgos (UBU) |
| instname_str | Universidad de Burgos (UBU) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:riubu.ubu.es:10259/5546 |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | American Chemical Society |
| publisherStr | American Chemical Society |
| reponame_str | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| spelling | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes Milián, Ana García García, Patricia Pérez Redondo, Adrián Sanz Díez, Roberto Vaquero, Juan J. Fernández Rodríguez, Manuel A. Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Química orgánica Chemistry, Organic Readily available o′-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evolution of the gold intermediate and plays a key role in the reaction outcome. Ministerio de Economıá y Competitividad (MINECO), AEI and FEDER (projects CTQ2017- 85263-R and CTQ2016-75023-C2-1-P), Instituto de Salud Carlos III (FEDER funds, ISCIII RETIC REDINREN RD16/ 0009/0015), Junta de Castilla y León and FEDER (BU291P18), and University of Alcalá (projects CCGP2017- EXP/016 and CCG2018/EXP-008 American Chemical Society http://hdl.handle.net/10259/5546 |
| spellingShingle | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes Milián, Ana Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Química orgánica Chemistry, Organic |
| status_str | acceptedVersion |
| title | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| title_full | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| title_fullStr | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| title_full_unstemmed | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| title_short | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| title_sort | Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes |
| topic | Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Química orgánica Chemistry, Organic |
| topic_facet | Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Química orgánica Chemistry, Organic |
| url | http://hdl.handle.net/10259/5546 |