Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks

Composting is an important waste management strategy, providing an economical and environment-friendly approach to sanitizing and stabilizing biosolids for land soil amendment. However, the resulting product can contain a large number of organic pollutants that may have adverse effects on the ecosys...

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Authors: Martín Bueno, Julia; Mejías Padilla, Carmen; Arenas Molina, Marina; Santos Morcillo, Juan Luis; Aparicio Gómez, Irene; Alonso Álvarez, Esteban
Format: Article
Status:Published version
Publication date:2022
Country:España
Institution:Universidad de Sevilla (US)
Repository:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/131141
Online Access:https://hdl.handle.net/11441/131141
https://doi.org/10.3390/su14010186
Access Level:Open access
Keyword:Linear alkylbenzene sulfonate
Nonylphenol ethoxylates
Di(2-ethylhexyl)phthalate
Occurrence
Composting processes
Risk assessment
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author Martín Bueno, Julia
author2 Mejías Padilla, Carmen
Arenas Molina, Marina
Santos Morcillo, Juan Luis
Aparicio Gómez, Irene
Alonso Álvarez, Esteban
author2_role author
author
author
author
author
author_browse Alonso Álvarez, Esteban
Aparicio Gómez, Irene
Arenas Molina, Marina
Martín Bueno, Julia
Mejías Padilla, Carmen
Santos Morcillo, Juan Luis
author_facet Martín Bueno, Julia
Mejías Padilla, Carmen
Arenas Molina, Marina
Santos Morcillo, Juan Luis
Aparicio Gómez, Irene
Alonso Álvarez, Esteban
author_role author
collection idUS. Depósito de Investigación de la Universidad de Sevilla
description Composting is an important waste management strategy, providing an economical and environment-friendly approach to sanitizing and stabilizing biosolids for land soil amendment. However, the resulting product can contain a large number of organic pollutants that may have adverse effects on the ecosystem. This paper presents the occurrence of eight widely used organic pollutants (four linear alkylbenzene sulfonates (LAS C10-C13), nonylphenol and its mono- and di-ethoxylates (NPE) and a di(2-ethylhexyl)phthalate (DEHP)) in full-scale composting processes. LAS homologues were detected at the highest concentrations (range of ∑LAS: 2068–9375 mg kg−1 dm), exceeding the limit fixed in the EU Directive draft. The concentration levels of the NPE and DEHP were significantly lower (up to 27.5 and 156.8 mg kg−1 dm, respectively) and did not exceed their fixed limits in the EU Directive draft. Ecotoxicological risk assessment for when compost is amended onto soils has also been evaluated. The concentrations measured represented a medium-low risk for most compounds, although it was not enough in the case of LAS C11 and C13 and NP.
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institution Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
network_acronym_str ES
network_name_str España
oai_identifier_str oai:idus.us.es:11441/131141
publishDate 2022
publishDateSort 2022
publisher MDPI
publisherStr MDPI
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
spelling Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks Martín Bueno, Julia Mejías Padilla, Carmen Arenas Molina, Marina Santos Morcillo, Juan Luis Aparicio Gómez, Irene Alonso Álvarez, Esteban Linear alkylbenzene sulfonate Nonylphenol ethoxylates Di(2-ethylhexyl)phthalate Occurrence Composting processes Risk assessment Composting is an important waste management strategy, providing an economical and environment-friendly approach to sanitizing and stabilizing biosolids for land soil amendment. However, the resulting product can contain a large number of organic pollutants that may have adverse effects on the ecosystem. This paper presents the occurrence of eight widely used organic pollutants (four linear alkylbenzene sulfonates (LAS C10-C13), nonylphenol and its mono- and di-ethoxylates (NPE) and a di(2-ethylhexyl)phthalate (DEHP)) in full-scale composting processes. LAS homologues were detected at the highest concentrations (range of ∑LAS: 2068–9375 mg kg−1 dm), exceeding the limit fixed in the EU Directive draft. The concentration levels of the NPE and DEHP were significantly lower (up to 27.5 and 156.8 mg kg−1 dm, respectively) and did not exceed their fixed limits in the EU Directive draft. Ecotoxicological risk assessment for when compost is amended onto soils has also been evaluated. The concentrations measured represented a medium-low risk for most compounds, although it was not enough in the case of LAS C11 and C13 and NP. Junta de Andalucía, Consejería de Economía, Conocimiento, Empresas y Universidad Project No. P20_00556 MDPI https://hdl.handle.net/11441/131141 https://doi.org/10.3390/su14010186
spellingShingle Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
Martín Bueno, Julia
Linear alkylbenzene sulfonate
Nonylphenol ethoxylates
Di(2-ethylhexyl)phthalate
Occurrence
Composting processes
Risk assessment
status_str publishedVersion
title Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
title_full Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
title_fullStr Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
title_full_unstemmed Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
title_short Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
title_sort Occurrence of linear alkylbenzene sulfonates, nonylphenol ethoxylates and di(2-ethylhexyl)phthalate in composting processes: Environmental risks
topic Linear alkylbenzene sulfonate
Nonylphenol ethoxylates
Di(2-ethylhexyl)phthalate
Occurrence
Composting processes
Risk assessment
topic_facet Linear alkylbenzene sulfonate
Nonylphenol ethoxylates
Di(2-ethylhexyl)phthalate
Occurrence
Composting processes
Risk assessment
url https://hdl.handle.net/11441/131141
https://doi.org/10.3390/su14010186