Flavanol–anthocyanin condensed pigments in plant extracts

[EN] Pigments resulting from the direct condensation of anthocyanins and flavanols are usually associated with reactions taking place during processing and storage of plant-derived foods and beverages and have been particularly studied in aged red wines. In this paper, small amounts of flavanol–anth...

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Autores: González Paramás, Ana María; Lopes da Silva, Fátima; Martín-López, Pilar; Macz-Pop, Glenda; González Manzano, Susana; Alcalde Eon, Cristina; Pérez-Alonso, José Joaquín; Escribano Bailón, María Teresa; Rivas Gonzalo, Julián C.; Santos Buelga, Celestino
Tipo de documento: Artículo
Estado:Published version
Fecha de publicación:2006
País:España
Institución:Universidad de Salamanca (USAL)
Repositorio:GREDOS. Repositorio Institucional de la Universidad de Salamanca
OAI Identifier:oai:gredos.usal.es:10366/141133
Acceso en línea:http://hdl.handle.net/10366/141133
Nivel de acceso:Acceso abierto
Palabra clave:Flavanol–anthocyanin
Condensed pigments
Strawberry
Runner bean
Purple corn
Grape skin
2417.17 Nutrición Vegetal
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author González Paramás, Ana María
author2 Lopes da Silva, Fátima
Martín-López, Pilar
Macz-Pop, Glenda
González Manzano, Susana
Alcalde Eon, Cristina
Pérez-Alonso, José Joaquín
Escribano Bailón, María Teresa
Rivas Gonzalo, Julián C.
Santos Buelga, Celestino
author2_role author
author
author
author
author
author
author
author
author
author_browse Alcalde Eon, Cristina
Escribano Bailón, María Teresa
González Manzano, Susana
González Paramás, Ana María
Lopes da Silva, Fátima
Macz-Pop, Glenda
Martín-López, Pilar
Pérez-Alonso, José Joaquín
Rivas Gonzalo, Julián C.
Santos Buelga, Celestino
author_facet González Paramás, Ana María
Lopes da Silva, Fátima
Martín-López, Pilar
Macz-Pop, Glenda
González Manzano, Susana
Alcalde Eon, Cristina
Pérez-Alonso, José Joaquín
Escribano Bailón, María Teresa
Rivas Gonzalo, Julián C.
Santos Buelga, Celestino
author_role author
collection GREDOS. Repositorio Institucional de la Universidad de Salamanca
description [EN] Pigments resulting from the direct condensation of anthocyanins and flavanols are usually associated with reactions taking place during processing and storage of plant-derived foods and beverages and have been particularly studied in aged red wines. In this paper, small amounts of flavanol–anthocyanin condensed pigments are found in different plant extracts. Structures are suggested for 10 such condensed pigments detected in extracts of strawberry, runner beans, purple corn and grape skins, based on their MSn fragmentation patterns, following analyses by electrospray tandem mass spectrometry. All of them correspond to dimers containing a flavan-3-ol [either (epi)afzelechin, (epi)catechin or (epi)gallocatechin] as the upper unit carbon–carbon linked to a lower anthocyanin unit consisting of different delphinidin, cyanidin, pelargonidin, peonidin or malvidin derivatives. The detection of these pigments in plant extracts may suggest that they are natural pigments and not products exclusively formed during storage and ageing of processed foods and beverages, as was previously assumed.
eu_rights_str_mv openAccess
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institution Universidad de Salamanca (USAL)
instname_str Universidad de Salamanca (USAL)
network_acronym_str ES
network_name_str España
oai_identifier_str oai:gredos.usal.es:10366/141133
publishDate 2006
publishDateSort 2006
reponame_str GREDOS. Repositorio Institucional de la Universidad de Salamanca
spelling Flavanol–anthocyanin condensed pigments in plant extracts González Paramás, Ana María Lopes da Silva, Fátima Martín-López, Pilar Macz-Pop, Glenda González Manzano, Susana Alcalde Eon, Cristina Pérez-Alonso, José Joaquín Escribano Bailón, María Teresa Rivas Gonzalo, Julián C. Santos Buelga, Celestino Flavanol–anthocyanin Condensed pigments Strawberry Runner bean Purple corn Grape skin 2417.17 Nutrición Vegetal [EN] Pigments resulting from the direct condensation of anthocyanins and flavanols are usually associated with reactions taking place during processing and storage of plant-derived foods and beverages and have been particularly studied in aged red wines. In this paper, small amounts of flavanol–anthocyanin condensed pigments are found in different plant extracts. Structures are suggested for 10 such condensed pigments detected in extracts of strawberry, runner beans, purple corn and grape skins, based on their MSn fragmentation patterns, following analyses by electrospray tandem mass spectrometry. All of them correspond to dimers containing a flavan-3-ol [either (epi)afzelechin, (epi)catechin or (epi)gallocatechin] as the upper unit carbon–carbon linked to a lower anthocyanin unit consisting of different delphinidin, cyanidin, pelargonidin, peonidin or malvidin derivatives. The detection of these pigments in plant extracts may suggest that they are natural pigments and not products exclusively formed during storage and ageing of processed foods and beverages, as was previously assumed. http://hdl.handle.net/10366/141133
spellingShingle Flavanol–anthocyanin condensed pigments in plant extracts
González Paramás, Ana María
Flavanol–anthocyanin
Condensed pigments
Strawberry
Runner bean
Purple corn
Grape skin
2417.17 Nutrición Vegetal
status_str publishedVersion
title Flavanol–anthocyanin condensed pigments in plant extracts
title_full Flavanol–anthocyanin condensed pigments in plant extracts
title_fullStr Flavanol–anthocyanin condensed pigments in plant extracts
title_full_unstemmed Flavanol–anthocyanin condensed pigments in plant extracts
title_short Flavanol–anthocyanin condensed pigments in plant extracts
title_sort Flavanol–anthocyanin condensed pigments in plant extracts
topic Flavanol–anthocyanin
Condensed pigments
Strawberry
Runner bean
Purple corn
Grape skin
2417.17 Nutrición Vegetal
topic_facet Flavanol–anthocyanin
Condensed pigments
Strawberry
Runner bean
Purple corn
Grape skin
2417.17 Nutrición Vegetal
url http://hdl.handle.net/10366/141133