Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles

Gold nanoparticles protected with a mixture of hexanothiol and MUA (11-mercaptoundecanoic acid) (AuNP1) were reacted with Co(II) tetraaminophtalocyanine (CoTAPc). The resulting nanoparticles formed via covalent bonds, AuNP2, were characterized by absorption spectra, infrared spectroscopy and transmi...

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Authors: Friederici, Mario; Angurell Purroy, Inmaculada; Rosell, Oriol; Seco García, Miquel Angel; Muller, Carlos; Llorca Piqué, Jordi|||0000-0002-7447-9582
Format: Article
Publication date:2015
Country:España
Institution:Universitat Politècnica de Catalunya (UPC)
Repository:UPCommons. Portal del coneixement obert de la UPC
Language:English
OAI Identifier:oai:upcommons.upc.edu:2117/83131
Online Access:https://hdl.handle.net/2117/83131
Access Level:Open access
Keyword:Electrochemistry
Nanoparticles
Electroquímica
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica
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author Friederici, Mario
author2 Angurell Purroy, Inmaculada
Rosell, Oriol
Seco García, Miquel Angel
Muller, Carlos
Llorca Piqué, Jordi|||0000-0002-7447-9582
author2_role author
author
author
author
author
author_browse Angurell Purroy, Inmaculada
Friederici, Mario
Llorca Piqué, Jordi|||0000-0002-7447-9582
Muller, Carlos
Rosell, Oriol
Seco García, Miquel Angel
author_facet Friederici, Mario
Angurell Purroy, Inmaculada
Rosell, Oriol
Seco García, Miquel Angel
Muller, Carlos
Llorca Piqué, Jordi|||0000-0002-7447-9582
author_role author
collection UPCommons. Portal del coneixement obert de la UPC
description Gold nanoparticles protected with a mixture of hexanothiol and MUA (11-mercaptoundecanoic acid) (AuNP1) were reacted with Co(II) tetraaminophtalocyanine (CoTAPc). The resulting nanoparticles formed via covalent bonds, AuNP2, were characterized by absorption spectra, infrared spectroscopy and transmission electron microscopy. Modified carbon paste electrodes were prepared with AuNP1, CoTAPc and AuNP2 and evaluated for electrochemical detection of L-cysteine by cyclic voltammetry. Sensing of L-cysteine was uniquely observed with the electrode modified with AuNP2
eu_rights_str_mv openAccess
format article
id ES_bd2a3a58ea13f3aa52a7b3ad4e93adf1
institution Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
language eng
network_acronym_str ES
network_name_str España
oai_identifier_str oai:upcommons.upc.edu:2117/83131
publishDate 2015
publishDateSort 2015
reponame_str UPCommons. Portal del coneixement obert de la UPC
spelling Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles Friederici, Mario Angurell Purroy, Inmaculada Rosell, Oriol Seco García, Miquel Angel Muller, Carlos Llorca Piqué, Jordi|||0000-0002-7447-9582 Electrochemistry Nanoparticles Electroquímica Nanopartícules Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica Gold nanoparticles protected with a mixture of hexanothiol and MUA (11-mercaptoundecanoic acid) (AuNP1) were reacted with Co(II) tetraaminophtalocyanine (CoTAPc). The resulting nanoparticles formed via covalent bonds, AuNP2, were characterized by absorption spectra, infrared spectroscopy and transmission electron microscopy. Modified carbon paste electrodes were prepared with AuNP1, CoTAPc and AuNP2 and evaluated for electrochemical detection of L-cysteine by cyclic voltammetry. Sensing of L-cysteine was uniquely observed with the electrode modified with AuNP2 https://hdl.handle.net/2117/83131
spellingShingle Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
Friederici, Mario
Electrochemistry
Nanoparticles
Electroquímica
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica
title Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
title_full Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
title_fullStr Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
title_full_unstemmed Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
title_short Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
title_sort Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles
topic Electrochemistry
Nanoparticles
Electroquímica
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica
topic_facet Electrochemistry
Nanoparticles
Electroquímica
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica
url https://hdl.handle.net/2117/83131