Aliphatic polyamides (nylons): Interplay between hydrogen bonds and crystalline structures, polymorphic transitions and crystallization

Aliphatic polyamides (nylons) constitute a family of polymers with outstanding properties and multiple applications. Despite the intensive research studies carried out with nylons, there are still multiple unsolved questions concerning crystallization processes, crystalline structures, polymorphic t...

Full description

Bibliographic Details
Author: Puiggalí Bellalta, Jordi|||0000-0002-0640-4474
Format: Article
Publication date:2021
Country:España
Institution:Universitat Politècnica de Catalunya (UPC)
Repository:UPCommons. Portal del coneixement obert de la UPC
Language:English
OAI Identifier:oai:upcommons.upc.edu:2117/356120
Online Access:https://hdl.handle.net/2117/356120
https://dx.doi.org/10.1002/pcr2.10199
Access Level:Open access
Keyword:Polymers
Polímers
Cristal·lització
Àrees temàtiques de la UPC::Enginyeria química
Description
Summary:Aliphatic polyamides (nylons) constitute a family of polymers with outstanding properties and multiple applications. Despite the intensive research studies carried out with nylons, there are still multiple unsolved questions concerning crystallization processes, crystalline structures, polymorphic transitions, and crystalline morphologies. Constrains imposed by the strong intermolecular interactions affect the amorphous state, the rigid amorphous phase, the molecular folding, the morphology and obviously the crystalline structure. Some of these relevant points are discussed in the present work.