Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system
BACKGROUND The recycling of CO2 by photo-electrochemical reduction has attracted wide interest due to its potential benefits when compared to electro-, and photo-catalysis approaches. Among the different available semiconductors, TiO2 is the most employed material in photo-electrochemical cells. Bes...
| Authors: | ; ; |
|---|---|
| Format: | Article |
| Publication date: | 2020 |
| Country: | España |
| Institution: | Universidad de Cantabria (UC) |
| Repository: | UCrea Repositorio Abierto de la Universidad de Cantabria |
| Language: | English |
| OAI Identifier: | oai:repositorio.unican.es:10902/18638 |
| Online Access: | http://hdl.handle.net/10902/18638 |
| Access Level: | Open access |
| Keyword: | Photoelectrocatalysis CO2 reduction TiO2 Cu Methanol Ethanol |
| _version_ | 1878735309031604224 |
|---|---|
| author | Castro González, Sergio |
| author2 | Albo Sánchez, Jonathan|||0000-0001-6781-5704 Irabien Gulías, Ángel|||0000-0002-2411-4163 |
| author2_role | author author |
| author_browse | Albo Sánchez, Jonathan|||0000-0001-6781-5704 Castro González, Sergio Irabien Gulías, Ángel|||0000-0002-2411-4163 |
| author_facet | Castro González, Sergio Albo Sánchez, Jonathan|||0000-0001-6781-5704 Irabien Gulías, Ángel|||0000-0002-2411-4163 |
| author_role | author |
| collection | UCrea Repositorio Abierto de la Universidad de Cantabria |
| description | BACKGROUND The recycling of CO2 by photo-electrochemical reduction has attracted wide interest due to its potential benefits when compared to electro-, and photo-catalysis approaches. Among the different available semiconductors, TiO2 is the most employed material in photo-electrochemical cells. Besides, Cu is a well-known electrocatalyst for alcohols production from CO2 reduction. RESULTS In this study, a photo-electrochemical cell consisting on a TiO2 photoanode Membrane Electrode Assembly (MEA) and a Cu plate are employed to reduce CO2 to methanol and ethanol continuously under UV illumination (100 mW·cm-2). A maximum increment of 4.3 mA·cm-2 in current between the illuminated and dark conditions is achieved at -2 V vs. Ag/AgCl. The continuous photo-electrochemical reduction process in the filter-press cell is evaluated in terms of reaction rate (r), as well as Faradaic (FE) and energy (EE) efficiencies. At -1.8 V vs. Ag/AgCl, a maximum reaction rate of r=-9.5 -mol·m-2·s-1, FE=-16.2 % and EE=-5.2 % for methanol, and r=-6.8 -mol·m-2·s-1, FE=-23.2 % and EE=-6.8 % for ethanol can be achieved. CONCLUSIONS The potential benefits of the photoanode-driven system, in terms of yields and efficiencies, are observed when employing a TiO2-based MEA photoanode and Cu as dark cathode. The results demonstrate first the effect of UV illumination on current density, and then the formation of alcohols from the continuous photoreduction of CO2. Increasing the external applied voltage led to an enhanced production of methanol, but decreases ethanol formation. The system outperforms previous photoanode-based systems for the CO2-to-alcohols reactions. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_7a2c64d3d3d7120be21d40f82a795a4e |
| institution | Universidad de Cantabria (UC) |
| instname_str | Universidad de Cantabria (UC) |
| language | eng |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:repositorio.unican.es:10902/18638 |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | Wiley-Blackwell |
| publisherStr | Wiley-Blackwell |
| reponame_str | UCrea Repositorio Abierto de la Universidad de Cantabria |
| spelling | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system Castro González, Sergio Albo Sánchez, Jonathan|||0000-0001-6781-5704 Irabien Gulías, Ángel|||0000-0002-2411-4163 Photoelectrocatalysis CO2 reduction TiO2 Cu Methanol Ethanol BACKGROUND The recycling of CO2 by photo-electrochemical reduction has attracted wide interest due to its potential benefits when compared to electro-, and photo-catalysis approaches. Among the different available semiconductors, TiO2 is the most employed material in photo-electrochemical cells. Besides, Cu is a well-known electrocatalyst for alcohols production from CO2 reduction. RESULTS In this study, a photo-electrochemical cell consisting on a TiO2 photoanode Membrane Electrode Assembly (MEA) and a Cu plate are employed to reduce CO2 to methanol and ethanol continuously under UV illumination (100 mW·cm-2). A maximum increment of 4.3 mA·cm-2 in current between the illuminated and dark conditions is achieved at -2 V vs. Ag/AgCl. The continuous photo-electrochemical reduction process in the filter-press cell is evaluated in terms of reaction rate (r), as well as Faradaic (FE) and energy (EE) efficiencies. At -1.8 V vs. Ag/AgCl, a maximum reaction rate of r=-9.5 -mol·m-2·s-1, FE=-16.2 % and EE=-5.2 % for methanol, and r=-6.8 -mol·m-2·s-1, FE=-23.2 % and EE=-6.8 % for ethanol can be achieved. CONCLUSIONS The potential benefits of the photoanode-driven system, in terms of yields and efficiencies, are observed when employing a TiO2-based MEA photoanode and Cu as dark cathode. The results demonstrate first the effect of UV illumination on current density, and then the formation of alcohols from the continuous photoreduction of CO2. Increasing the external applied voltage led to an enhanced production of methanol, but decreases ethanol formation. The system outperforms previous photoanode-based systems for the CO2-to-alcohols reactions. The authors gratefully acknowledge the financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) through the projects CTQ2016-76231-C2-1-R and Ramón y Cajal programme (RYC-2015-17080). Wiley-Blackwell http://hdl.handle.net/10902/18638 |
| spellingShingle | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system Castro González, Sergio Photoelectrocatalysis CO2 reduction TiO2 Cu Methanol Ethanol |
| title | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| title_full | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| title_fullStr | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| title_full_unstemmed | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| title_short | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| title_sort | Continuous conversion of CO2 to alcohols in a TiO2 photoanode-driven photoelectrochemical system |
| topic | Photoelectrocatalysis CO2 reduction TiO2 Cu Methanol Ethanol |
| topic_facet | Photoelectrocatalysis CO2 reduction TiO2 Cu Methanol Ethanol |
| url | http://hdl.handle.net/10902/18638 |