Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives
The sole effect of the microstructure of biodegradable isodimorphic poly(butylene succinate)-ran-poly(ε-caprolactone) random copolyesters on their rheological properties is investigated. To avoid the effect of molecular weight and temperature, two rheological procedures are considered: the activatio...
| Authors: | ; ; ; ; ; |
|---|---|
| Format: | Article |
| Publication date: | 2022 |
| Country: | España |
| Institution: | Universidad del País Vasco |
| Repository: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/55512 |
| Online Access: | http://hdl.handle.net/10810/55512 |
| Access Level: | Open access |
| Keyword: | PBS-ran-PCL activation energy of flow microstructure rheology tackiness HMA |
| _version_ | 1878734324966096896 |
|---|---|
| author | Sandoval, Aleida J. |
| author2 | Fernández San Martín, Mercedes Candal, María Virginia Safari, Maryam Santamaría Ibarburu, Pedro Antonio Müller Sánchez, Alejandro Jesús |
| author2_role | author author author author author |
| author_browse | Candal, María Virginia Fernández San Martín, Mercedes Müller Sánchez, Alejandro Jesús Safari, Maryam Sandoval, Aleida J. Santamaría Ibarburu, Pedro Antonio |
| author_facet | Sandoval, Aleida J. Fernández San Martín, Mercedes Candal, María Virginia Safari, Maryam Santamaría Ibarburu, Pedro Antonio Müller Sánchez, Alejandro Jesús |
| author_role | author |
| collection | Addi. Archivo Digital para la Docencia y la Investigación |
| description | The sole effect of the microstructure of biodegradable isodimorphic poly(butylene succinate)-ran-poly(ε-caprolactone) random copolyesters on their rheological properties is investigated. To avoid the effect of molecular weight and temperature, two rheological procedures are considered: the activation energy of flow, Ea, and the phase angle versus complex modulus plots. An unexpected variation of both parameters with copolyester composition is observed, with respective maximum and minimum values for the 50/50 composition. This might be due to the peculiar chain configurations of the copolymers that vary as a function of comonomer distribution within the chains. The same chain configuration variations are responsible for the isodimorphic character of the copolymers in the crystalline state. Tack tests, performed to study the viability of the copolyesters as environmentally friendly hot melt adhesives (HMA), reveal a correlation with rheological results. Tackiness parameters, particularly the energy of adhesion obtained from stress-strain curves during debonding experiments, are enhanced as melt elasticity increases. Based on the carried-out analysis, the link microstructure-rheology-tackiness is established, allowing selecting the best performing HMA sample considering the polymer chemistry of the system. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_67cbc4e36ec1ee4483c84750eec4e865 |
| institution | Universidad del País Vasco |
| instname_str | Universidad del País Vasco |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:addi.ehu.eus:10810/55512 |
| publishDate | 2022 |
| publishDateSort | 2022 |
| publisher | MDPI |
| publisherStr | MDPI |
| reponame_str | Addi. Archivo Digital para la Docencia y la Investigación |
| spelling | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives Sandoval, Aleida J. Fernández San Martín, Mercedes Candal, María Virginia Safari, Maryam Santamaría Ibarburu, Pedro Antonio Müller Sánchez, Alejandro Jesús PBS-ran-PCL activation energy of flow microstructure rheology tackiness HMA The sole effect of the microstructure of biodegradable isodimorphic poly(butylene succinate)-ran-poly(ε-caprolactone) random copolyesters on their rheological properties is investigated. To avoid the effect of molecular weight and temperature, two rheological procedures are considered: the activation energy of flow, Ea, and the phase angle versus complex modulus plots. An unexpected variation of both parameters with copolyester composition is observed, with respective maximum and minimum values for the 50/50 composition. This might be due to the peculiar chain configurations of the copolymers that vary as a function of comonomer distribution within the chains. The same chain configuration variations are responsible for the isodimorphic character of the copolymers in the crystalline state. Tack tests, performed to study the viability of the copolyesters as environmentally friendly hot melt adhesives (HMA), reveal a correlation with rheological results. Tackiness parameters, particularly the energy of adhesion obtained from stress-strain curves during debonding experiments, are enhanced as melt elasticity increases. Based on the carried-out analysis, the link microstructure-rheology-tackiness is established, allowing selecting the best performing HMA sample considering the polymer chemistry of the system. We acknowledge the financial support from the BIODEST project; this project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 778092. This work has also received funding from the Basque Government through grant IT1309-19. MDPI http://hdl.handle.net/10810/55512 |
| spellingShingle | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives Sandoval, Aleida J. PBS-ran-PCL activation energy of flow microstructure rheology tackiness HMA |
| title | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| title_full | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| title_fullStr | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| title_full_unstemmed | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| title_short | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| title_sort | Rheology and Tack Properties of Biodegradable Isodimorphic Poly(butylene succinate)-Ran-Poly(ε-caprolactone) Random Copolyesters and Their Potential Use as Adhesives |
| topic | PBS-ran-PCL activation energy of flow microstructure rheology tackiness HMA |
| topic_facet | PBS-ran-PCL activation energy of flow microstructure rheology tackiness HMA |
| url | http://hdl.handle.net/10810/55512 |