From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reduct...
| Authors: | ; ; |
|---|---|
| Format: | Article |
| Publication date: | 2024 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/480089 |
| Online Access: | http://hdl.handle.net/2072/480089 https://doi.org/10.1039/D4QO02143F |
| Access Level: | Open access |
| Keyword: | Química 54 |
| _version_ | 1878734069759475712 |
|---|---|
| author | Tóth, Balázs L. |
| author2 | Amos, Stephanie G. E. Kleij, Arjan W. |
| author2_role | author author |
| author_browse | Amos, Stephanie G. E. Kleij, Arjan W. Tóth, Balázs L. |
| author_facet | Tóth, Balázs L. Amos, Stephanie G. E. Kleij, Arjan W. |
| author_role | author |
| collection | Recercat. Dipósit de la Recerca de Catalunya |
| description | Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene–yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon–carbon bond formation and beyond. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_62a216d8abfe15d4c19fdec29f1ed8a1 |
| institution | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| instname_str | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:recercat.cat:2072/480089 |
| publishDate | 2024 |
| publishDateSort | 2024 |
| publisher | Royal Society of Chemistry |
| publisherStr | Royal Society of Chemistry |
| reponame_str | Recercat. Dipósit de la Recerca de Catalunya |
| spelling | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes Tóth, Balázs L. Amos, Stephanie G. E. Kleij, Arjan W. Química 54 Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene–yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon–carbon bond formation and beyond. info:eu-repo/semantics/acceptedVersion Royal Society of Chemistry http://hdl.handle.net/2072/480089 https://doi.org/10.1039/D4QO02143F |
| spellingShingle | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes Tóth, Balázs L. Química 54 |
| title | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| title_full | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| title_fullStr | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| title_full_unstemmed | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| title_short | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| title_sort | From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes |
| topic | Química 54 |
| topic_facet | Química 54 |
| url | http://hdl.handle.net/2072/480089 https://doi.org/10.1039/D4QO02143F |