[2,6-Bis(2-pyrimidinylthiomethyl)pyridine]dichlorocopper(II) methanol solvate

In the title compound [CuCl2(C15H13N5S2].CH3OH, the Cu2+ ion has square-pyramidal coordination geometry. The basal plane of the pyramid is formed by two Cl- ions, one pyridine N atom and one pyrimidine N atom. The fifth coordination site is occupied by the S atom of a thiomethyl group. The methanol...

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Detalles Bibliográficos
Autores: Kivekäs, Raikko; Sillanpää, Reijo; Escriche, Lluís|||0000-0003-2562-5034; Sánchez-Castelló, G.; Casabó i Gispert, Jaume
Tipo de documento: Artículo
Fecha de publicación:1994
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Lenguaje:Inglés
OAI Identifier:oai:ddd.uab.cat:27744
Acceso en línea:https://ddd.uab.cat/record/27744
https://dx.doi.org/urn:doi:10.1107/S0108270193013629
Nivel de acceso:Acceso abierto
Palabra clave:Cristal·lografia
Crystallography
Descripción
Sumario:In the title compound [CuCl2(C15H13N5S2].CH3OH, the Cu2+ ion has square-pyramidal coordination geometry. The basal plane of the pyramid is formed by two Cl- ions, one pyridine N atom and one pyrimidine N atom. The fifth coordination site is occupied by the S atom of a thiomethyl group. The methanol molecule occupies an otherwise empty space in the structure.