Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines
We propose a method for determination of transition probabilities by laser-induced breakdown spectroscopy that avoids the error due to self-absorption. The method relies on CSigma graphs, a generalization of curves of growth which allows including several lines of various elements in the same ioniza...
| Authors: | ; ; |
|---|---|
| Format: | Article |
| Status: | Accepted version |
| Publication date: | 2015 |
| Country: | España |
| Institution: | Universidad San Jorge (USJ) |
| Repository: | Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| OAI Identifier: | oai:academica-e.unavarra.es:2454/17444 |
| Online Access: | https://hdl.handle.net/2454/17444 |
| Access Level: | Open access |
| Keyword: | Transition probabilities Laser induced breakdown spectroscopy CSigma graph Ca II |
| _version_ | 1878733632573538304 |
|---|---|
| author | Aguilera Andoaga, José Antonio |
| author2 | Aragón Garbizu, Carlos Manrique Rosel, Javier |
| author2_role | author author |
| author_browse | Aguilera Andoaga, José Antonio Aragón Garbizu, Carlos Manrique Rosel, Javier |
| author_facet | Aguilera Andoaga, José Antonio Aragón Garbizu, Carlos Manrique Rosel, Javier |
| author_role | author |
| collection | Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| description | We propose a method for determination of transition probabilities by laser-induced breakdown spectroscopy that avoids the error due to self-absorption. The method relies on CSigma graphs, a generalization of curves of growth which allows including several lines of various elements in the same ionization state. CSigma graphs are constructed including reference lines of an emitting species with well-known transition probabilities, together with the lines of interest, both in the same ionization state. The samples are fused glass disks prepared from small concentrations of compounds. When the method is applied, the concentration of the element of interest in the sample must be controlled to avoid the failure of the homogeneous plasma model. To test the method, the transition probabilities of 9 Ca II lines arising from the 4d, 5s, 5d and 6s configurations are measured using Fe II reference lines. The data for 5 of the studied lines, mainly from the 5d and 6s configurations, had not been measured previously. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_59f10d78aceb3a00a3aa0a37014aaae5 |
| institution | Universidad San Jorge (USJ) |
| instname_str | Universidad San Jorge (USJ) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:academica-e.unavarra.es:2454/17444 |
| publishDate | 2015 |
| publishDateSort | 2015 |
| publisher | Elsevier |
| publisherStr | Elsevier |
| reponame_str | Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| spelling | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines Aguilera Andoaga, José Antonio Aragón Garbizu, Carlos Manrique Rosel, Javier Transition probabilities Laser induced breakdown spectroscopy CSigma graph Ca II We propose a method for determination of transition probabilities by laser-induced breakdown spectroscopy that avoids the error due to self-absorption. The method relies on CSigma graphs, a generalization of curves of growth which allows including several lines of various elements in the same ionization state. CSigma graphs are constructed including reference lines of an emitting species with well-known transition probabilities, together with the lines of interest, both in the same ionization state. The samples are fused glass disks prepared from small concentrations of compounds. When the method is applied, the concentration of the element of interest in the sample must be controlled to avoid the failure of the homogeneous plasma model. To test the method, the transition probabilities of 9 Ca II lines arising from the 4d, 5s, 5d and 6s configurations are measured using Fe II reference lines. The data for 5 of the studied lines, mainly from the 5d and 6s configurations, had not been measured previously. This work has been supported by the project FIS2011-29521 of the Spanish Ministerio de Economía y Competitividad. Elsevier https://hdl.handle.net/2454/17444 |
| spellingShingle | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines Aguilera Andoaga, José Antonio Transition probabilities Laser induced breakdown spectroscopy CSigma graph Ca II |
| status_str | acceptedVersion |
| title | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| title_full | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| title_fullStr | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| title_full_unstemmed | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| title_short | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| title_sort | Method for measurement of transition probabilities by laser-induced breakdown spectroscopy based on CSigma graphs. Application to Ca II spectral lines |
| topic | Transition probabilities Laser induced breakdown spectroscopy CSigma graph Ca II |
| topic_facet | Transition probabilities Laser induced breakdown spectroscopy CSigma graph Ca II |
| url | https://hdl.handle.net/2454/17444 |