Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temp...
| Autores: | ; ; ; ; |
|---|---|
| Tipo de documento: | Artículo |
| Fecha de publicación: | 1999 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/23349 |
| Acceso en línea: | http://hdl.handle.net/11441/23349 |
| Nivel de acceso: | Acceso abierto |
| _version_ | 1878733003505532929 |
|---|---|
| author | Castro Arroyo, Miguel Ángel |
| author2 | Clarke, Stuart M. Inaba, Akira Arnold, Thomas Thomas, Robert K. |
| author2_role | author author author author |
| author_browse | Arnold, Thomas Castro Arroyo, Miguel Ángel Clarke, Stuart M. Inaba, Akira Thomas, Robert K. |
| author_facet | Castro Arroyo, Miguel Ángel Clarke, Stuart M. Inaba, Akira Arnold, Thomas Thomas, Robert K. |
| author_role | author |
| collection | idUS. Depósito de Investigación de la Universidad de Sevilla |
| description | Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temperature of the pure pentane but at a temperature very similar to that of the bulk material. The lower melting point of the bulk pentane in the pentane/graphite system, when it is present in a relatively small amount, allows the melting point of the solid monolayer to be clearly resolved. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_4e30df5d02f9c024aa6489ee866bd7ce |
| institution | Universidad de Sevilla (US) |
| instname_str | Universidad de Sevilla (US) |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:idus.us.es:11441/23349 |
| publishDate | 1999 |
| publishDateSort | 1999 |
| reponame_str | idUS. Depósito de Investigación de la Universidad de Sevilla |
| spelling | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface Castro Arroyo, Miguel Ángel Clarke, Stuart M. Inaba, Akira Arnold, Thomas Thomas, Robert K. Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temperature of the pure pentane but at a temperature very similar to that of the bulk material. The lower melting point of the bulk pentane in the pentane/graphite system, when it is present in a relatively small amount, allows the melting point of the solid monolayer to be clearly resolved. http://hdl.handle.net/11441/23349 |
| spellingShingle | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface Castro Arroyo, Miguel Ángel |
| title | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| title_full | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| title_fullStr | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| title_full_unstemmed | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| title_short | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| title_sort | Anomalous behaviour of pentane adsorbed at the graphite/liquid interface |
| url | http://hdl.handle.net/11441/23349 |