Structural caracterization of silver(I) complexes of diphenylmethanimine and (diphenylmethyleneamino)diphenylphosphine

The reaction of NH=CPH2 with the silver species [AgX(PPh3)] (X=ClO4, SO3CF3) affords the derivatives [Ag(PPh3)(NH=CPh2)]X. Complexes [Ag(Ph2PN=CPh2)2]X (X=Cl, ClO4, SO3CF3) have been obtained from Ph2PN=CPh2 and the corresponding silver salt AgX. X-ray diffraction studies have been carried out for f...

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Authors: Codina, A.; Crespo, O.; Fernández, E.J. [0000-0002-6501-744X]; Jones, P.G.; Laguna, A. [0000-0003-1984-7538]; López-De-Luzuriaga, J.M. [0000-0001-5767-8734]; Olmos, M.E. [0000-0001-8890-8977]
Format: Article
Status:Published version
Publication date:2003
Country:España
Institution:Universidad de La Rioja (UR)
Repository:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc6841b750603269e80584
Online Access:https://investigacion.unirioja.es/documentos/5bbc6841b750603269e80584
Access Level:Open access
Keyword:Crystal structures
Ketimine complexes
Silver complexes
Summary:The reaction of NH=CPH2 with the silver species [AgX(PPh3)] (X=ClO4, SO3CF3) affords the derivatives [Ag(PPh3)(NH=CPh2)]X. Complexes [Ag(Ph2PN=CPh2)2]X (X=Cl, ClO4, SO3CF3) have been obtained from Ph2PN=CPh2 and the corresponding silver salt AgX. X-ray diffraction studies have been carried out for four of the derivatives. © 2002 Elsevier Science B.V. All rights reserved.

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