Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry
The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance...
| Authors: | ; ; ; ; ; |
|---|---|
| Format: | Article |
| Status: | Accepted version |
| Publication date: | 2017 |
| Country: | España |
| Institution: | Universidad de Barcelona |
| Repository: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/125567 |
| Online Access: | https://hdl.handle.net/2445/125567 |
| Access Level: | Open access |
| Keyword: | Pal·ladi (Element químic) Voltametria Palladium Voltammetry |
| _version_ | 1878732003032956928 |
|---|---|
| author | Pérez Ràfols, Clara |
| author2 | Trechera, Pedro Serrano i Plana, Núria Díaz Cruz, José Manuel Ariño Blasco, Cristina Esteban i Cortada, Miquel |
| author2_role | author author author author author |
| author_browse | Ariño Blasco, Cristina Díaz Cruz, José Manuel Esteban i Cortada, Miquel Pérez Ràfols, Clara Serrano i Plana, Núria Trechera, Pedro |
| author_facet | Pérez Ràfols, Clara Trechera, Pedro Serrano i Plana, Núria Díaz Cruz, José Manuel Ariño Blasco, Cristina Esteban i Cortada, Miquel |
| author_role | author |
| collection | Dipòsit Digital de la UB |
| description | The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance as compared to a commercially sputtered bismuth screen-printed electrode (BispSPE). The detection and quantification limits were 2.7 and 9.0 µg L-1 respectively with a good linear behaviour in the wide examined concentration range (from 1 µg L-1 up to 100.0 µg L1, R2= 0.998). The proposed ex-situ SbSPCE showed an excellent repeatability with a relative standard deviation of 0.5 % for ten successive measurements and a very good reproducibility (1.6 % for three different ex-situ SbSPCE units within series of ten repetitive assays). Moreover, the ex-situ SbSPCE was successfully applied for the determination of low concentration levels of Pd(II) in spiked tap water with a very high reproducibility (0.2 %) and providing equivalent results to those achieved by ICP-MS measurements |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_3aef697c8cfccb3fd22ee5a771c5b03f |
| institution | Universidad de Barcelona |
| instname_str | Universidad de Barcelona |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:diposit.ub.edu:2445/125567 |
| publishDate | 2017 |
| publishDateSort | 2017 |
| publisher | Elsevier B.V. |
| publisherStr | Elsevier B.V. |
| reponame_str | Dipòsit Digital de la UB |
| spelling | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry Pérez Ràfols, Clara Trechera, Pedro Serrano i Plana, Núria Díaz Cruz, José Manuel Ariño Blasco, Cristina Esteban i Cortada, Miquel Pal·ladi (Element químic) Voltametria Palladium Voltammetry The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance as compared to a commercially sputtered bismuth screen-printed electrode (BispSPE). The detection and quantification limits were 2.7 and 9.0 µg L-1 respectively with a good linear behaviour in the wide examined concentration range (from 1 µg L-1 up to 100.0 µg L1, R2= 0.998). The proposed ex-situ SbSPCE showed an excellent repeatability with a relative standard deviation of 0.5 % for ten successive measurements and a very good reproducibility (1.6 % for three different ex-situ SbSPCE units within series of ten repetitive assays). Moreover, the ex-situ SbSPCE was successfully applied for the determination of low concentration levels of Pd(II) in spiked tap water with a very high reproducibility (0.2 %) and providing equivalent results to those achieved by ICP-MS measurements Elsevier B.V. https://hdl.handle.net/2445/125567 |
| spellingShingle | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry Pérez Ràfols, Clara Pal·ladi (Element químic) Voltametria Palladium Voltammetry |
| status_str | acceptedVersion |
| title | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| title_full | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| title_fullStr | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| title_full_unstemmed | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| title_short | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| title_sort | Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry |
| topic | Pal·ladi (Element químic) Voltametria Palladium Voltammetry |
| topic_facet | Pal·ladi (Element químic) Voltametria Palladium Voltammetry |
| url | https://hdl.handle.net/2445/125567 |