New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane

X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd...

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Authors: Rajabalee, Fazil Ahmad; Metivaud, Valérie; Mondieig, Denise, 1958-; Haget, Yvette; Cuevas Diarte, Miguel Ángel
Format: Article
Status:Published version
Publication date:1999
Country:España
Institution:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repository:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/18201
Online Access:https://hdl.handle.net/2445/18201
Access Level:Open access
Keyword:Alcans
Difracció de raigs X
Alkanes
X-rays diffraction
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author Rajabalee, Fazil Ahmad
author2 Metivaud, Valérie
Mondieig, Denise, 1958-
Haget, Yvette
Cuevas Diarte, Miguel Ángel
author2_role author
author
author
author
author_browse Cuevas Diarte, Miguel Ángel
Haget, Yvette
Metivaud, Valérie
Mondieig, Denise, 1958-
Rajabalee, Fazil Ahmad
author_facet Rajabalee, Fazil Ahmad
Metivaud, Valérie
Mondieig, Denise, 1958-
Haget, Yvette
Cuevas Diarte, Miguel Ángel
author_role author
collection Recercat. Dipósit de la Recerca de Catalunya
description X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd-odd binary systems with D n = 2, the three domains are not all orthorhombic. This work has enabled us to show that two of the domains are, in fact, monoclinic, (Aa, Z = 4) and the other one is orthorhombic (Pca21, Z = 4). The conclusions drawn in this work can be easily transposed to other binary systems of n-alkanes.
eu_rights_str_mv openAccess
format article
id ES_3a2f9d3c67d0b96d760ff93ae2b7ca77
institution Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
network_acronym_str ES
network_name_str España
oai_identifier_str oai:recercat.cat:2445/18201
publishDate 1999
publishDateSort 1999
publisher Materials Research Society
publisherStr Materials Research Society
reponame_str Recercat. Dipósit de la Recerca de Catalunya
spelling New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane Rajabalee, Fazil Ahmad Metivaud, Valérie Mondieig, Denise, 1958- Haget, Yvette Cuevas Diarte, Miguel Ángel Alcans Difracció de raigs X Alkanes X-rays diffraction X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd-odd binary systems with D n = 2, the three domains are not all orthorhombic. This work has enabled us to show that two of the domains are, in fact, monoclinic, (Aa, Z = 4) and the other one is orthorhombic (Pca21, Z = 4). The conclusions drawn in this work can be easily transposed to other binary systems of n-alkanes. Materials Research Society https://hdl.handle.net/2445/18201
spellingShingle New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
Rajabalee, Fazil Ahmad
Alcans
Difracció de raigs X
Alkanes
X-rays diffraction
status_str publishedVersion
title New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
title_full New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
title_fullStr New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
title_full_unstemmed New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
title_short New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
title_sort New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
topic Alcans
Difracció de raigs X
Alkanes
X-rays diffraction
topic_facet Alcans
Difracció de raigs X
Alkanes
X-rays diffraction
url https://hdl.handle.net/2445/18201