Optimization of Laccase/Mediator System (LMS) Stage Applied in Fractionation of Eucalyptus globulus

In a biorefinery framework, a laccase/mediator system treatment following autohydrolysis was carried out for eucalyptus wood prior to soda-anthraquinone pulping. The enzymatic and autohydrolysis conditions, with a view to maximizing the extraction of hemicelluloses while preserving the integrity of...

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Bibliographic Details
Authors: Loaiza Rodríguez, Javier Mauricio; Alfaro Martínez, Ascensión; López Baldovín, Francisco; García Domínguez, María Trinidad; García Domínguez, Juan Carlos
Format: Article
Publication date:2019
Country:España
Institution:Universidad de Huelva (UHU)
Repository:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Language:English
OAI Identifier:oai:ariasmontano.uhu.es:10272/16315
Online Access:http://hdl.handle.net/10272/16315
Access Level:Open access
Keyword:Autohydrolysis
Eucalyptus globulus
Laccase
Hemicellulose
Pulp
Soda-AQ
Description
Summary:In a biorefinery framework, a laccase/mediator system treatment following autohydrolysis was carried out for eucalyptus wood prior to soda-anthraquinone pulping. The enzymatic and autohydrolysis conditions, with a view to maximizing the extraction of hemicelluloses while preserving the integrity of glucan, were optimized. Secondly, pulping of solid phase from Eucalyptus globulus wood autohydrolysis and the enzymatic process was carried out and compared with a conventional soda-anthraquinone (AQ) pulping process. The prehydrolysis and enzymatic delignification of the raw material prior to the delignification with soda- Anthraquinone (AQ) results in paper sheets with a lower kappa number and brightness and strength properties close to conventional soda-AQ paper and a liquid fraction rich in hemicellulose compounds that can be used in additional ways. The advantage of this biorefinery scheme is that it requires a lower concentration of chemical reagents, and lower operating times and temperature in the alkaline delignification stage, which represents an economic and environmental improvement over the conventional process.