Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly
We report on the synthesis of a series of cyano-luminogens with cyanostilbene fragments, benzamide units, and a nonplanar biphenyl core. Benzamide units drive supramolecular polymerization, forming helical H aggregates via kinetically controlled self-assembly. A sergeants-and-soldiers experiment rev...
| Authors: | ; ; ; |
|---|---|
| Format: | Article |
| Publication date: | 2025 |
| Country: | España |
| Institution: | Universidad Complutense de Madrid (UCM) |
| Repository: | Docta Complutense |
| Language: | English |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/122597 |
| Online Access: | https://hdl.handle.net/20.500.14352/122597 |
| Access Level: | Open access |
| Keyword: | 547 Química orgánica (Química) 2306 Química Orgánica |
| _version_ | 1878731393841758208 |
|---|---|
| author | Fernández, Miguel |
| author2 | López-Gandul, Lucía Gómez Aspe, Rafael Sánchez Martín, Luis |
| author2_role | author author author |
| author_browse | Fernández, Miguel Gómez Aspe, Rafael López-Gandul, Lucía Sánchez Martín, Luis |
| author_facet | Fernández, Miguel López-Gandul, Lucía Gómez Aspe, Rafael Sánchez Martín, Luis |
| author_role | author |
| collection | Docta Complutense |
| description | We report on the synthesis of a series of cyano-luminogens with cyanostilbene fragments, benzamide units, and a nonplanar biphenyl core. Benzamide units drive supramolecular polymerization, forming helical H aggregates via kinetically controlled self-assembly. A sergeants-and-soldiers experiment revealed frustrated asymmetry amplification due to the contamination of linear dichroism. The planarization of the central π-conjugated systems enhances aggregation-induced emission affording circularly polarized luminescence-active helical aggregates. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_2eb5126e16b5a7e1794c19dbdb3c52da |
| institution | Universidad Complutense de Madrid (UCM) |
| instname_str | Universidad Complutense de Madrid (UCM) |
| language | eng |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:docta.ucm.es:20.500.14352/122597 |
| publishDate | 2025 |
| publishDateSort | 2025 |
| reponame_str | Docta Complutense |
| spelling | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly Fernández, Miguel López-Gandul, Lucía Gómez Aspe, Rafael Sánchez Martín, Luis 547 Química orgánica (Química) 2306 Química Orgánica We report on the synthesis of a series of cyano-luminogens with cyanostilbene fragments, benzamide units, and a nonplanar biphenyl core. Benzamide units drive supramolecular polymerization, forming helical H aggregates via kinetically controlled self-assembly. A sergeants-and-soldiers experiment revealed frustrated asymmetry amplification due to the contamination of linear dichroism. The planarization of the central π-conjugated systems enhances aggregation-induced emission affording circularly polarized luminescence-active helical aggregates. https://hdl.handle.net/20.500.14352/122597 |
| spellingShingle | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly Fernández, Miguel 547 Química orgánica (Química) 2306 Química Orgánica |
| title | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| title_full | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| title_fullStr | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| title_full_unstemmed | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| title_short | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| title_sort | Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly |
| topic | 547 Química orgánica (Química) 2306 Química Orgánica |
| topic_facet | 547 Química orgánica (Química) 2306 Química Orgánica |
| url | https://hdl.handle.net/20.500.14352/122597 |