Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems

The main objective of the present work is to develop and prove a theoretical explanation based on the Extended Non-Equilibrium Thermodynamics (ENETs) for the hysteretical thermoelectric behavior observed in certain thin-film photovoltaic materials. The ENET introduces dissipative fluxes in the entro...

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Authors: Palma, Roberto; Pérez-Aparicio, José L.; Bravo, R.
Format: Article
Publication date:2013
Country:España
Institution:Universitat Politècnica de València (UPV)
Repository:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Language:English
OAI Identifier:oai:riunet.upv.es:10251/74281
Online Access:https://riunet.upv.es/handle/10251/74281
Access Level:Open access
Keyword:Thin-film
Thermoelectric
Hysteresis
Finite element method
Extended thermodynamics
Relaxation times
Inverse problems
MECANICA DE LOS MEDIOS CONTINUOS Y TEORIA DE ESTRUCTURAS
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author Palma, Roberto
author2 Pérez-Aparicio, José L.
Bravo, R.
author2_role author
author
author_browse Bravo, R.
Palma, Roberto
Pérez-Aparicio, José L.
author_facet Palma, Roberto
Pérez-Aparicio, José L.
Bravo, R.
author_role author
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
description The main objective of the present work is to develop and prove a theoretical explanation based on the Extended Non-Equilibrium Thermodynamics (ENETs) for the hysteretical thermoelectric behavior observed in certain thin-film photovoltaic materials. The ENET introduces dissipative fluxes in the entropy balance that could explain this behavior. To verify this explanation from a numerical point of view, results are generated using a Finite Element (FE) formulation based on the ENET and already developed in previous publications by the authors. In addition, an identification Inverse Problem (IP) is formulated; a cost function is defined as the quadratic difference between experimental and numerical results and the IP is solved minimizing the cost function using genetic algorithms. The conclusion is that the loop-like distributions are due to energy dissipation introduced by dissipative fluxes that are closely related with relaxation times. Also, the FE-IP combination permits to find an approximated characterization of properties for several materials from single experimental curves. Finally, several numerical simulations are proposed for laboratory experiments to further validate the theoretical interpretation and to confirm the relation between relaxation times and hysteresis.
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language eng
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publishDate 2013
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reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
spelling Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems Palma, Roberto Pérez-Aparicio, José L. Bravo, R. Thin-film Thermoelectric Hysteresis Finite element method Extended thermodynamics Relaxation times Inverse problems MECANICA DE LOS MEDIOS CONTINUOS Y TEORIA DE ESTRUCTURAS The main objective of the present work is to develop and prove a theoretical explanation based on the Extended Non-Equilibrium Thermodynamics (ENETs) for the hysteretical thermoelectric behavior observed in certain thin-film photovoltaic materials. The ENET introduces dissipative fluxes in the entropy balance that could explain this behavior. To verify this explanation from a numerical point of view, results are generated using a Finite Element (FE) formulation based on the ENET and already developed in previous publications by the authors. In addition, an identification Inverse Problem (IP) is formulated; a cost function is defined as the quadratic difference between experimental and numerical results and the IP is solved minimizing the cost function using genetic algorithms. The conclusion is that the loop-like distributions are due to energy dissipation introduced by dissipative fluxes that are closely related with relaxation times. Also, the FE-IP combination permits to find an approximated characterization of properties for several materials from single experimental curves. Finally, several numerical simulations are proposed for laboratory experiments to further validate the theoretical interpretation and to confirm the relation between relaxation times and hysteresis. This research was partially supported by the Grants CSD2008-00037 Canfranc Underground Physics, Excelencia Junta Andalucia P08-TEP-03641 and Polytechnic University of Valencia under programs PAID 02-11-1828 and 05-10-2674. Elsevier https://riunet.upv.es/handle/10251/74281
spellingShingle Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
Palma, Roberto
Thin-film
Thermoelectric
Hysteresis
Finite element method
Extended thermodynamics
Relaxation times
Inverse problems
MECANICA DE LOS MEDIOS CONTINUOS Y TEORIA DE ESTRUCTURAS
title Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
title_full Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
title_fullStr Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
title_full_unstemmed Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
title_short Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
title_sort Study of hysteretic thermoelectric behavior in photovoltaic materials using the finite element method, extended thermodynamics and inverse problems
topic Thin-film
Thermoelectric
Hysteresis
Finite element method
Extended thermodynamics
Relaxation times
Inverse problems
MECANICA DE LOS MEDIOS CONTINUOS Y TEORIA DE ESTRUCTURAS
topic_facet Thin-film
Thermoelectric
Hysteresis
Finite element method
Extended thermodynamics
Relaxation times
Inverse problems
MECANICA DE LOS MEDIOS CONTINUOS Y TEORIA DE ESTRUCTURAS
url https://riunet.upv.es/handle/10251/74281