Picking the lock of coordination cage catalysis
[EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the acti...
| Authors: | ; ; ; ; |
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| Format: | Article |
| Publication date: | 2023 |
| Country: | España |
| Institution: | Universitat Politècnica de València (UPV) |
| Repository: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Language: | English |
| OAI Identifier: | oai:riunet.upv.es:10251/209239 |
| Online Access: | https://riunet.upv.es/handle/10251/209239 |
| Access Level: | Open access |
| Keyword: | Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| _version_ | 1878730218337730560 |
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| author | Piskorz, Tomasz K. |
| author2 | Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 |
| author2_role | author author author author |
| author_browse | Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 Piskorz, Tomasz K. Spicer, Rebecca |
| author_facet | Piskorz, Tomasz K. Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 |
| author_role | author |
| collection | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| description | [EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the active site of an enzyme. While there are now a growing collection of coordination cages that show highly proficient catalysis, exhibiting both excellent activity and efficient turnover, this number is still small compared to the vast library of metal¿organic structures that are known. In this review, we will attempt to unpick and discuss the key features that make an effective coordination cage catalyst, linking structure to activity (and selectivity) using lessons learnt from both experimental and computational analysis of the most notable exemplars. We will also provide an outlook for this area, reasoning why coordination cages have the potential to become the gold-standard in (synthetic) non-covalent catalysis. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | ES_17e20b769ca6f0b4e64e5c5dd5990621 |
| institution | Universitat Politècnica de València (UPV) |
| instname_str | Universitat Politècnica de València (UPV) |
| language | eng |
| network_acronym_str | ES |
| network_name_str | España |
| oai_identifier_str | oai:riunet.upv.es:10251/209239 |
| publishDate | 2023 |
| publishDateSort | 2023 |
| publisher | The Royal Society of Chemistry |
| publisherStr | The Royal Society of Chemistry |
| reponame_str | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| spelling | Picking the lock of coordination cage catalysis Piskorz, Tomasz K. Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA [EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the active site of an enzyme. While there are now a growing collection of coordination cages that show highly proficient catalysis, exhibiting both excellent activity and efficient turnover, this number is still small compared to the vast library of metal¿organic structures that are known. In this review, we will attempt to unpick and discuss the key features that make an effective coordination cage catalyst, linking structure to activity (and selectivity) using lessons learnt from both experimental and computational analysis of the most notable exemplars. We will also provide an outlook for this area, reasoning why coordination cages have the potential to become the gold-standard in (synthetic) non-covalent catalysis. T. K. P., P. J. L., and F. D. acknowledge the nancial support from EPSRC (EP/W010666/1 and EP/W009803/1). V. M.-C.acknowledges the nancial support from Generalitat Valenciana (CIDEGENT/2020/031). The Royal Society of Chemistry https://riunet.upv.es/handle/10251/209239 |
| spellingShingle | Picking the lock of coordination cage catalysis Piskorz, Tomasz K. Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| title | Picking the lock of coordination cage catalysis |
| title_full | Picking the lock of coordination cage catalysis |
| title_fullStr | Picking the lock of coordination cage catalysis |
| title_full_unstemmed | Picking the lock of coordination cage catalysis |
| title_short | Picking the lock of coordination cage catalysis |
| title_sort | Picking the lock of coordination cage catalysis |
| topic | Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| topic_facet | Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| url | https://riunet.upv.es/handle/10251/209239 |