Colored anodizing of titanium with pyroligneous solutions of black wattle
ABSTRACT In many places, charcoal production, using Australian Blackwood, is still a rudimentary process, generating huge environmental impact, due to the release of pyrolysis smoke into the atmosphere. Both the society and governmental agencies is pushing the factories to condense the smoke, genera...
| Authors: | ; ; ; ; ; ; ; |
|---|---|
| Format: | Article |
| Status: | Published version |
| Publication date: | 2020 |
| Country: | Brasil |
| Institution: | RLAM |
| Repository: | Matéria (Rio de Janeiro. Online) |
| Language: | English |
| OAI Identifier: | oai:scielo:S1517-70762020000200349 |
| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200349 |
| Access Level: | Open access |
| Keyword: | Pyroligneous liquor Titanium Anodizing |
| _version_ | 1878753230087782400 |
|---|---|
| author | Fuhr,Luciane Taís |
| author2 | Moura,Ângela Beatrice Dewes Carone,Carlos Leonardo Pandolfo Morisso,Fernando Dal Pont Scheffel,Leonardo Felix Kunst,Sandra Raquel Ferreira,Jane Zoppas Oliveira,Cláudia Trindade |
| author2_role | author author author author author author author |
| author_browse | Carone,Carlos Leonardo Pandolfo Ferreira,Jane Zoppas Fuhr,Luciane Taís Kunst,Sandra Raquel Morisso,Fernando Dal Pont Moura,Ângela Beatrice Dewes Oliveira,Cláudia Trindade Scheffel,Leonardo Felix |
| author_facet | Fuhr,Luciane Taís Moura,Ângela Beatrice Dewes Carone,Carlos Leonardo Pandolfo Morisso,Fernando Dal Pont Scheffel,Leonardo Felix Kunst,Sandra Raquel Ferreira,Jane Zoppas Oliveira,Cláudia Trindade |
| author_role | author |
| collection | Matéria (Rio de Janeiro. Online) |
| description | ABSTRACT In many places, charcoal production, using Australian Blackwood, is still a rudimentary process, generating huge environmental impact, due to the release of pyrolysis smoke into the atmosphere. Both the society and governmental agencies is pushing the factories to condense the smoke, generating byproduct known as pyroligneous liquor. Although it's largely used for agricultural purpose, as a fertilizer and phytosanitizer, its chemical composition presents hydrogen and oxygen rich compounds, making it a potential electrolyte in the surface treatment industry, especially for anodization. Organic alternatives are being used to replace these electrolytes to make the anodizing process cleaner. Then, for the first time, Australian Blackwood pyroligneous liquor was used as an anodizing electrolyte for titanium TICP-G2, to obtain oxides for protection and coloring of the metal. For such, suitable parameters to execute the process were determined (dilution, current density, temperature, agitation, pH, conductivity) and an analysis of the transient potential over time was made. The anodized surfaces were characterized using top view Scan Electronic Microscopy (SEM) and Grazing Incidence X-ray Diffraction (GIXRD). Based on the results presented, it can be concluded that the best parameters to anodize the titanium were obtained with 50% pyroligneous liquor diluted in water, obtaining colored surfaces and promoting the formation of oxide crystallites clusters mainly in longer process times (3600s). |
| eu_rights_str_mv | openAccess |
| format | article |
| id | BR_339cd1300a5b8ec6bcfaf41b22686f8f |
| institution | RLAM |
| instname_str | Matéria (Rio de Janeiro. Online) |
| language | eng |
| network_acronym_str | BR |
| network_name_str | Brasil |
| oai_identifier_str | oai:scielo:S1517-70762020000200349 |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
| publisherStr | Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
| reponame_str | Matéria (Rio de Janeiro. Online) |
| spelling | Colored anodizing of titanium with pyroligneous solutions of black wattle Fuhr,Luciane Taís Moura,Ângela Beatrice Dewes Carone,Carlos Leonardo Pandolfo Morisso,Fernando Dal Pont Scheffel,Leonardo Felix Kunst,Sandra Raquel Ferreira,Jane Zoppas Oliveira,Cláudia Trindade Pyroligneous liquor Titanium Anodizing ABSTRACT In many places, charcoal production, using Australian Blackwood, is still a rudimentary process, generating huge environmental impact, due to the release of pyrolysis smoke into the atmosphere. Both the society and governmental agencies is pushing the factories to condense the smoke, generating byproduct known as pyroligneous liquor. Although it's largely used for agricultural purpose, as a fertilizer and phytosanitizer, its chemical composition presents hydrogen and oxygen rich compounds, making it a potential electrolyte in the surface treatment industry, especially for anodization. Organic alternatives are being used to replace these electrolytes to make the anodizing process cleaner. Then, for the first time, Australian Blackwood pyroligneous liquor was used as an anodizing electrolyte for titanium TICP-G2, to obtain oxides for protection and coloring of the metal. For such, suitable parameters to execute the process were determined (dilution, current density, temperature, agitation, pH, conductivity) and an analysis of the transient potential over time was made. The anodized surfaces were characterized using top view Scan Electronic Microscopy (SEM) and Grazing Incidence X-ray Diffraction (GIXRD). Based on the results presented, it can be concluded that the best parameters to anodize the titanium were obtained with 50% pyroligneous liquor diluted in water, obtaining colored surfaces and promoting the formation of oxide crystallites clusters mainly in longer process times (3600s). Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200349 |
| spellingShingle | Colored anodizing of titanium with pyroligneous solutions of black wattle Fuhr,Luciane Taís Pyroligneous liquor Titanium Anodizing |
| status_str | publishedVersion |
| title | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| title_full | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| title_fullStr | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| title_full_unstemmed | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| title_short | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| title_sort | Colored anodizing of titanium with pyroligneous solutions of black wattle |
| topic | Pyroligneous liquor Titanium Anodizing |
| topic_facet | Pyroligneous liquor Titanium Anodizing |
| url | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200349 |