Seed-mediated growth of jack-shaped gold nanoparticles from cyclodextrin-coated gold nanospheres
Branched gold nanoparticles were prepared by a seed-mediated approach using per-6-thio-6-deoxy-β-cyclodextrin capped gold nanospheres as seeds and a growth medium similar to those commonly employed to prepare gold nanorods, containing AgNO3, ascorbic acid and cetyltrimethylammonium bromide. Novel ja...
| Autores: | ; ; ; ; ; ; |
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| Tipo de documento: | Artigo |
| Estado: | Published version |
| Data de publicação: | 2013 |
| País: | Argentina |
| Recursos: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositório: | CONICET Digital (CONICET) |
| Idioma: | Inglês |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/25716 |
| Acesso em linha: | http://hdl.handle.net/11336/25716 |
| Nível de acesso: | Acesso aberto |
| Palavra-chave: | Jack-Shaped Gold Nanoparticles Hydrogen Peroxide https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/2.8 |
| Resumo: | Branched gold nanoparticles were prepared by a seed-mediated approach using per-6-thio-6-deoxy-β-cyclodextrin capped gold nanospheres as seeds and a growth medium similar to those commonly employed to prepare gold nanorods, containing AgNO3, ascorbic acid and cetyltrimethylammonium bromide. Novel jack-shaped gold nanoparticles (102–105 nm) were obtained at a specific range of Ag+ ion concentrations (62–102 μM). The crystalline structure of these nanoparticles was confirmed by high-resolution transmission electron microscopy. The influence of the perthiolated β-cyclodextrin on the successful preparation of gold nanojacks was demonstrated. The jack-shaped gold nanoparticles showed strong absorption in the near infrared region and excellent catalytic activity for the electrochemical oxidation of H2O2. |
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