Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant c...
| Authors: | ; ; ; ; |
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| Format: | Article |
| Status: | Published version |
| Publication date: | 2023 |
| Country: | Argentina |
| Institution: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repository: | CONICET Digital (CONICET) |
| Language: | English |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/224878 |
| Online Access: | http://hdl.handle.net/11336/224878 |
| Access Level: | Open access |
| Keyword: | BIOACTIVE DFT EUTECTIC SOLVENT MANGIFERIN MANGO https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| _version_ | 1878403421328900096 |
|---|---|
| author | Ojeda, Gonzalo Adrian |
| author2 | Vallejos, Margarita Sgroppo, Sonia Cecilia Sánchez Moreno, Concepción de Ancos, Begoña |
| author2_role | author author author author |
| author_browse | Ojeda, Gonzalo Adrian Sgroppo, Sonia Cecilia Sánchez Moreno, Concepción Vallejos, Margarita de Ancos, Begoña |
| author_facet | Ojeda, Gonzalo Adrian Vallejos, Margarita Sgroppo, Sonia Cecilia Sánchez Moreno, Concepción de Ancos, Begoña |
| author_role | author |
| collection | CONICET Digital (CONICET) |
| description | Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | AR_7b4e926fb83dccade27ea12eeca7aa9d |
| identifier_str_mv | Ojeda, Gonzalo Adrian; Vallejos, Margarita; Sgroppo, Sonia Cecilia; Sánchez Moreno, Concepción; de Ancos, Begoña; Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents; Elsevier; Heliyon; 9; 6; 6-2023; 1-14 2405-8440 CONICET Digital CONICET |
| institution | Consejo Nacional de Investigaciones Científicas y Técnicas |
| instname_str | Consejo Nacional de Investigaciones Científicas y Técnicas |
| language | eng |
| network_acronym_str | AR |
| network_name_str | Argentina |
| oai_identifier_str | oai:ri.conicet.gov.ar:11336/224878 |
| publishDate | 2023 |
| publishDateSort | 2023 |
| publisher | Elsevier |
| publisherStr | Elsevier |
| reponame_str | CONICET Digital (CONICET) |
| spelling | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents Ojeda, Gonzalo Adrian Vallejos, Margarita Sgroppo, Sonia Cecilia Sánchez Moreno, Concepción de Ancos, Begoña BIOACTIVE DFT EUTECTIC SOLVENT MANGIFERIN MANGO https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties. Fil: Ojeda, Gonzalo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina Fil: Vallejos, Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina Fil: Sgroppo, Sonia Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina Fil: Sánchez Moreno, Concepción. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnologia de Alimentos y Nutrición; España Fil: de Ancos, Begoña. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnologia de Alimentos y Nutrición; España Elsevier http://hdl.handle.net/11336/224878 Ojeda, Gonzalo Adrian; Vallejos, Margarita; Sgroppo, Sonia Cecilia; Sánchez Moreno, Concepción; de Ancos, Begoña; Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents; Elsevier; Heliyon; 9; 6; 6-2023; 1-14 2405-8440 CONICET Digital CONICET |
| spellingShingle | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents Ojeda, Gonzalo Adrian BIOACTIVE DFT EUTECTIC SOLVENT MANGIFERIN MANGO https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| status_str | publishedVersion |
| title | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| title_full | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| title_fullStr | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| title_full_unstemmed | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| title_short | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| title_sort | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
| topic | BIOACTIVE DFT EUTECTIC SOLVENT MANGIFERIN MANGO https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic_facet | BIOACTIVE DFT EUTECTIC SOLVENT MANGIFERIN MANGO https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| url | http://hdl.handle.net/11336/224878 |