SERS from pyridine adsorbed on electrodispersed platinum electrodes

SERS of pyridine adsorbed on electrodispersed platinum electrodes is reported. Electrodispersed platinum surfaces are obtained by electroreducing hydrous platinum oxide layers. The intensity of the Raman scattering for adsorbed pyridine is enhanced by at least one order of magnitude, after normalizi...

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Detalles Bibliográficos
Autores: Bilmes, Sara Aldabe; Rubim, J. C.; Otto, A.; Arvia, Alejandro Jorge
Tipo de documento: Artículo
Estado:Published version
Fecha de publicación:1989
País:Argentina
Institución:UNLP
Repositorio:SEDICI (UNLP)
Lenguaje:Inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/126588
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/126588
Nivel de acceso:Acceso abierto
Palabra clave:Ciencias Exactas
Química
platinum electrodes
SERS
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author Bilmes, Sara Aldabe
author2 Rubim, J. C.
Otto, A.
Arvia, Alejandro Jorge
author2_role author
author
author
author_browse Arvia, Alejandro Jorge
Bilmes, Sara Aldabe
Otto, A.
Rubim, J. C.
author_facet Bilmes, Sara Aldabe
Rubim, J. C.
Otto, A.
Arvia, Alejandro Jorge
author_role author
collection SEDICI (UNLP)
description SERS of pyridine adsorbed on electrodispersed platinum electrodes is reported. Electrodispersed platinum surfaces are obtained by electroreducing hydrous platinum oxide layers. The intensity of the Raman scattering for adsorbed pyridine is enhanced by at least one order of magnitude, after normalizing with respect to the area increase. The estimated Raman enhancement factor is lower than that reported for roughened silver electrodes but it is still sufficiently large to allow Raman scattering from adsorbates on platinum to be detectable. Surface changes (ageing) of the metal surface can be also followed by SERS.
eu_rights_str_mv openAccess
format article
id AR_6cdf2db1678eace0bc7fe7c7b6a4e60d
institution UNLP
instname_str Universidad Nacional de La Plata
language eng
network_acronym_str AR
network_name_str Argentina
oai_identifier_str oai:sedici.unlp.edu.ar:10915/126588
publishDate 1989
publishDateSort 1989
reponame_str SEDICI (UNLP)
spelling SERS from pyridine adsorbed on electrodispersed platinum electrodes Bilmes, Sara Aldabe Rubim, J. C. Otto, A. Arvia, Alejandro Jorge Ciencias Exactas Química platinum electrodes SERS SERS of pyridine adsorbed on electrodispersed platinum electrodes is reported. Electrodispersed platinum surfaces are obtained by electroreducing hydrous platinum oxide layers. The intensity of the Raman scattering for adsorbed pyridine is enhanced by at least one order of magnitude, after normalizing with respect to the area increase. The estimated Raman enhancement factor is lower than that reported for roughened silver electrodes but it is still sufficiently large to allow Raman scattering from adsorbates on platinum to be detectable. Surface changes (ageing) of the metal surface can be also followed by SERS. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas http://sedici.unlp.edu.ar/handle/10915/126588
spellingShingle SERS from pyridine adsorbed on electrodispersed platinum electrodes
Bilmes, Sara Aldabe
Ciencias Exactas
Química
platinum electrodes
SERS
status_str publishedVersion
title SERS from pyridine adsorbed on electrodispersed platinum electrodes
title_full SERS from pyridine adsorbed on electrodispersed platinum electrodes
title_fullStr SERS from pyridine adsorbed on electrodispersed platinum electrodes
title_full_unstemmed SERS from pyridine adsorbed on electrodispersed platinum electrodes
title_short SERS from pyridine adsorbed on electrodispersed platinum electrodes
title_sort SERS from pyridine adsorbed on electrodispersed platinum electrodes
topic Ciencias Exactas
Química
platinum electrodes
SERS
topic_facet Ciencias Exactas
Química
platinum electrodes
SERS
url http://sedici.unlp.edu.ar/handle/10915/126588