Comment on "Magnetoresistance and phase composition of La-Sn-Mn-O systems"

In a published paper by Li et al. [Phys. Rev. B 60, 10284 (1999)] the transport properties and phase composition of the manganites La1-xSnxMnO3+δ (x=0.1-0.5) are studied. The authors analyze their results assuming the existence of two phases: a perovskite LaMnO3+δ and a pyrochlore (La0.5Sn0.5)2Mn2O7...

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Detalles Bibliográficos
Autores: Caneiro, Alberto; Morales, L.; Prado, F.; Lamas, Diego Germán; Sanchez, Rodolfo Daniel; Serquis, Adriana Cristina
Tipo de documento: Artículo
Estado:Published version
Fecha de publicación:2000
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Lenguaje:Inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/68583
Acceso en línea:http://hdl.handle.net/11336/68583
Nivel de acceso:Acceso abierto
Palabra clave:Magnetoresistance
Manganites
La-Sn-Mn-O System
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descripción
Sumario:In a published paper by Li et al. [Phys. Rev. B 60, 10284 (1999)] the transport properties and phase composition of the manganites La1-xSnxMnO3+δ (x=0.1-0.5) are studied. The authors analyze their results assuming the existence of two phases: a perovskite LaMnO3+δ and a pyrochlore (La0.5Sn0.5)2Mn2O7. We consider that they misinterpret the x-ray diffraction data and we conclude that the manganites La1-xSnxMnO3+δ are in fact a multiphase material composed by LaMnO3+δ, La2Sn2O7, Mn3O4, and SnO2. The magnetic transition observed by Mössbauer experiments around 65 K attributed by Li et al. to that of the (La0.5Sn0.5)2Mn2O7 pyrochlore phase would correspond to that of the paramagnetic-ferrimagnetic one of Fe-doped Mn3O4.