Zur Kristallstruktur der gemischten Phosphat/Sulfat-Fluorapatite

It is shown that the apatite phases of composition Ca₁₀₋ₓNaₓ(PO₄)₆₋ₓ(SO₄)ₓF2 crystallize in a monoclinic unit cell, which is related to those of pure fluoroapatite by doubling the 6b-parameter. Some comparisons with related systems are made and a possible explanation for the origin of the small mono...

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Detalles Bibliográficos
Autores: Apella, María Cristina; Baran, Enrique José
Tipo de documento: Artículo
Estado:Published version
Fecha de publicación:1981
País:Argentina
Institución:UNLP
Repositorio:SEDICI (UNLP)
Lenguaje:Idioma no determinado
OAI Identifier:oai:sedici.unlp.edu.ar:10915/120746
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/120746
Nivel de acceso:Acceso abierto
Palabra clave:Química
Phosphate-sulfate-apatites
Crystal data
Structural behaviour
Descripción
Sumario:It is shown that the apatite phases of composition Ca₁₀₋ₓNaₓ(PO₄)₆₋ₓ(SO₄)ₓF2 crystallize in a monoclinic unit cell, which is related to those of pure fluoroapatite by doubling the 6b-parameter. Some comparisons with related systems are made and a possible explanation for the origin of the small monoclinic distortion is advanced.