Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)

Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc...

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Autores: Bartolomé, F.; Bun¿u, O.; García, L.M.; Natoli, C.R.; Piantek, M.; Pascual, J.I.; Schuller, I.K.; Gredig, T.; Wilhelm, F.; Rogalev, A.; Bartolomé, J.
Tipo de documento: Artículo
Estado:Published version
Fecha de publicación:2015
País:España
Institución:Universidad de Zaragoza
Repositorio:Zaguán. Repositorio Digital de la Universidad de Zaragoza
OAI Identifier:oai:zaguan.unizar.es:46544
Acceso en línea:http://zaguan.unizar.es/record/46544
Nivel de acceso:Acceso abierto
Sumario:Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc molecules is different from that found in bulk a and ß phases. Moreover, the molecules do not lay parallel to the surface of the substrate. These structural findings are relevant to understand magnetism of FePc films.

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